ASSEMBLIES AND METHODS OF STABILIZATION
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United States of America Patent
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Issued Date -
Oct 15, 2015
app pub date -
Nov 21, 2013
filing date -
Nov 21, 2012
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Abstract
Some embodiments of the present invention provide an assembly for harvesting light comprising a first molecule joined to a metal oxide surface through a surface linking group and a second molecule joined to the metal oxide surface. Such assemblies can harvest light to do useful chemistry, such as in a dye-sensitized photoelectrochemical cell, or a molecular catalyst-solar cell system. In other embodiments, the harvested light can be converted into electricity, such as in a dye-sensitized solar cell. Other embodiments of the present invention provide methods for stabilizing a chromophore or a catalyst on a surface. These methods are applicable, for example, to dye-sensitized photoelectrochemical cells where the surface-bound chromophores are known to be unstable under aqueous conditions.
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