FREE RADICAL AND CONTROLLED RADICAL POLYMERIZATION PROCESSES USING AZIDE RADICAL INITIATORS
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United States of America Patent
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Issued Date -
Feb 26, 2015
app pub date -
Aug 21, 2014
filing date -
Aug 23, 2013
priority date (Note) -
Abandoned
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Abstract
A process is described comprising polymerizing at least one unsaturated monomer (e.g., fluorine substituted alkene monomer) in the presence of an azide radical initiator and a solvent, under reaction conditions and for a time sufficient to polymerize the at least one unsaturated monomer to form a polymer. The present disclosure provides a method for the synthesis of polymers with 100% azide chain end functionality, for living/controlled radical polymerization of unsaturated monomers (e.g., fluorine substituted alkene monomers) and for the synthesis of complex polymer architectures, using azide click reactions.
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