NEGATIVE ELECTRODE MATERIAL FOR LITHIUM ION BATTERIES CONTAINING SURFACE-FLUORINATED B-TYPE TITANIUM OXIDE POWDER, METHOD FOR PRODUCING SAME, AND LITHIUM ION BATTERY USING SAME
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United States of America Patent
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Issued Date -
Jun 19, 2014
app pub date -
Jul 26, 2012
filing date -
Jul 29, 2011
priority date (Note) -
Abandoned
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Abstract
A problem to be solved is to enhance the charge and discharge characteristics and rate characteristics of a B-type titanium oxide (TiO2(B)) powder by a simple treatment and to provide a B-type titanium oxide powder that can be suitably used as a negative electrode material for a lithium ion battery. A B-type titanium oxide powder is allowed to undergo a reaction under a fluorine-containing gas atmosphere at 0° C. to 200° C. for 1 minute to 10 days to obtain a surface-fluorinated B-type titanium oxide powder. It is preferred that the fluorination treatment is performed at 0.01 atm to 2 atm. It is preferred that a gas containing a fluorine compound selected from a fluorine (F2) gas, a nitrogen trifluoride (NF3) gas, a perfluorotrimethylamine (N(CF3)3) gas, a chlorine trifluoride (ClF3) gas and the like is used as the fluorine-containing gas.
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