PROCESS FOR CONTROLLING THE RELATIVE ACTIVITY OF ACTIVE CENTERS OF CATALYST SYSTEMS COMPRISING AT LEAST ONE LATE TRANSITION METAL CATALYST COMPONENT AND AT LEAST ONE ZIEGLER CATALYST COMPONENT
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United States of America Patent
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Oct 17, 2013
app pub date -
Dec 19, 2011
filing date -
Dec 22, 2010
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Abstract
A method of controlling the polymer composition of an ethylene copolymer in a process for preparing ethylene copolymers by copolymerizing ethylene and at least one other olefin in the presence of a polymerization catalyst system comprising at least one late transition metal catalyst component (A) having a tridentate ligand which bears at least two ortho, ortho′-disubstituted aryl radicals, at least one Ziegler catalyst component (B), and at least one activating compound (C) by varying the polymerization temperature, a process for copolymerizing ethylene and at least one other olefin in the presence of such a polymerization catalyst system comprising utilizing the controlling method, a method for altering the polymer composition of an ethylene copolymer obtained by copolymerizing ethylene and at least one other olefin in the presence of such a polymerization catalyst system by varying the polymerization temperature and a method for transitioning from one ethylene copolymer grade to another by using the method for altering the polymer composition.
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