Gas and liquid phase catalytic Beckmann rearrangement of oximes to produce lactams

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United States of America Patent

PATENT NO 8772476
APP PUB NO 20130109851A1
SERIAL NO

13658495

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Abstract

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Methods for producing lactams from oximes by performing a Beckmann rearrangement using a silicoaluminophosphate catalyst are provided. These catalysts may be used in gas phase or liquid phase reactions to convert oximes into lactams. High conversion of oxime and high selectivity for the desired lactams are produced using the disclosed methods, including high conversion and selectivity for ε-caprolactam produced from cyclohexanone oxime and high conversion and selectivity for ω-laurolactam produced from cyclododecanone oxime.

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  • ADVANSIX RESINS & CHEMICALS LLC;UNIVERSITY OF SOUTHAMPTON

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  • 2012 Application Filing Year
  • C07D Class
  • 4683 Applications Filed
  • 3679 Patents Issued To-Date
  • 78.57 % Issued To-Date
Click to zoom InYear of Issuance% of Matters IssuedCumulative IssuancesYearly Issuances2012201320142015201620172018201920202021202220230255075100

Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Levy, Alan B Randolph, US 17 66
Potter, Matthew E Southampton, GB 5 5
Raja, Robert Eastleigh, GB 23 57

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  • 2 Citation Count
  • C07D Class
  • 28.38 % this patent is cited more than
  • 11 Age
Citation count rangeNumber of patents cited in rangeNumber of patents cited in various citation count ranges8331701255833610822501 - 1011 - 2021 - 3031 - 4041 - 5051 - 6061 - 7081 - 90100 +0100200300400500600700800900100011001200130014001500160017001800

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