Process for preparing arylamines

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United States of America Patent

APP PUB NO 20080039633A1
SERIAL NO

11836440

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ATTORNEY / AGENT: (SPONSORED)

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Abstract

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The invention relates to a process for preparing arylamines or heteroarylamines or arylamides or heteroarylamides by cross-coupling of primary or secondary amines or amides with substituted aryl or heteroaryl compounds in the presence of a Bronsted base and a catalyst or precatalyst, wherein the catalyst comprises a) a transition metal, a complex, a salt or a compound of this transition metal selected from the group consisting of Ni, Pd and b) at least one ligand selected from the group consisting of bidentate bis(phosphino)alkanediyls having the following formula in a solvent or solvent mixture, where the radicals Ar.sup.1-4 are each, independently of one another, an aryl or heteroaryl substituent selected from the group consisting of phenyl, naphthyl, pyridyl and biphenyl or Ar.sup.1-4 is hydrogen, C.sub.1-, C.sub.2-alkyl, straight-chain, branched or cyclic C.sub.3-C.sub.8-alkyl, and L is an alkanediyl bridge which has from 1 to 20 carbon atoms.

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Patent Owner(s)

Patent OwnerAddress
ARCHIMICA GMBHFRANKFURT GERMANY

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
JUNG, Joerg Floersheim, DE 15 112
Lehnemann, Bernd Wilheilm Frankfurt am Main, DE 1 11
Meudt, Andreas Hofheim, DE 49 279

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