Solid catalyst component and process for the (co) polymerization of ethylene

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United States of America Patent

APP PUB NO 20070072764A1
SERIAL NO

10578873

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Abstract

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Catalyst and solid component of catalyst for the (co)polymerization of ethylene, comprising titanium, magnesium, chlorine, a protic organo-oxygenated compound D.sub.p and a neutral aprotic electron-donor compound D, in the following molar ranges: Mg/Ti=1.0-50; D/Ti=1.0-15; Cl/Ti=6.0-100; D.sub.p/D=0.05-3; and a process for obtaining said component comprising the following steps in succession: (a) formation of a mixture and dissolution, in said electron-donor aprotic compound D, of a magnesium chloride and a titanium compound having formula (II): Ti.sup.v(OR.sub.3).sub.aX.sub.(v-a) wherein each R.sub.3 independently represents a hydrocarbyl or acyl radical having from 1 to 15 carbon atoms; each X is selected from chlorine, bromine or iodine; 'v' has the value of 3 or 4, and 'a' is a number varying from 0 to 'v', with a molar ratio between titanium and magnesium ranging from 1/1 to 50/1; (b) partial separation of the compound D from said mixture prepared in step (a) until a residue is obtained, solid at room temperature, wherein the D/Ti ratio ranges from 1.5 to 40, (c) formation of a suspension of said solid organo-oxygenated protic compound D.sub.p, in such a quantity that the molar ratio D.sub.p/D ranges from 0.1 to 1.2 and maintaining the mixture until equilibrium is reached, to form the desired solid component of catalyst.

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Patent Owner(s)

Patent OwnerAddress
POLIMERI EUROPA S P AITALY BRINDISI BRINDISI BRINDISI

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Adesso, Corrado Brindisi, IT 3 7
Conti, Giuseppe Milano, IT 15 56
Masi, Francesco Lodi, IT 75 239
Menconi, Francesco Milano, IT 11 42

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