Bimodal polyethylene copolymers

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United States of America Patent

PATENT NO 11945938
APP PUB NO 20230272197A1
SERIAL NO

18303656

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Abstract

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Ethylene-based polymers are characterized by a density from 0.92 to 0.955 g/cm3, a HLMI of less than 35 g/10 min, and a ratio of a number of short chain branches (SCBs) per 1000 total carbon atoms at Mz to a number of SCBs per 1000 total carbon atoms at Mn in a range from 11.5 to 22. These polymers can have a higher molecular weight (HMW) component and a lower molecular weight (LMW) component, in which a ratio of a number of SCBs per 1000 total carbon atoms at Mn of the HMW component to a number of SCBs per 1000 total carbon atoms at Mn of the LMW component is in a range from 10.5 to 22. These ethylene polymers can be produced using a dual catalyst system containing an unbridged metallocene compound with an indenyl group having at least one halogen-substituted hydrocarbyl substituent with at least two halogen atoms, and a single atom bridged metallocene compound with a fluorenyl group and a cyclopentadienyl group.

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Patent Owner(s)

Patent OwnerAddress
CHEVRON PHILLIPS CHEMICAL COMPANY LP10001 SIX PINES DRIVE THE WOODLANDS TX 77380

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Lief, Graham R Bartlesville, US 24 30
Yang, Qing Bartlesville, US 496 9882
Yu, Youlu Bartlesville, US 83 1682

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