Tri-(adamantyl)phosphines and applications thereof
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United States of America
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Apr 20, 2021
Grant Date -
Oct 25, 2018
app pub date -
Oct 31, 2016
filing date -
Oct 31, 2016
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Abstract
In one aspect, phosphine compounds comprising three adamantyl moieties (PAd3) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAd3 ligands are also provided for catalytic synthesis including catalytic cross-coupling reactions.
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