SiN selective etch to SiO2 with non-plasma dry process for 3D NAND device applications

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United States of America

PATENT NO 10529581
APP PUB NO 20190206696A1
SERIAL NO

15858342

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Abstract

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Methods for isotropic etching at least a portion of a silicon-containing layer on a sidewall of high-aspect-ratio (HAR) apertures formed on a substrate in a reaction chamber are disclosed. The HAR aperture formed by plasma etching a stack of alternating layers of a first silicon-containing layer and a second silicon-containing layer, the second silicon-containing layer is different from the first silicon-containing layer. The method comprising the steps of: a) introducing a fluorine containing etching gas selected from the group consisting of nitrosyl fluoride (FNO), trifluoroamine oxide (F3NO), nitryl fluoride (FNO2) and combinations thereof into the reaction chamber; and b) removing at least a portion of the second silicon-containing layers by selectively etching the second silicon-containing layers versus the first silicon-containing layers with the fluorine containing etching gas to produce recesses between the first silicon-containing layers on the sidewall of the HAR aperture. Alternatively, the disclosed etching processes are cyclic etching processes.

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Patent Owner(s)

Patent OwnerAddress
L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEPARIS FRANCE PARIS PARIS

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Hsu, Chih-Yu Tskukuba, JP 50 210
Shen, Peng Tsukuba, JP 43 200
Stafford, Nathan Damascus, US 40 432
Teramoto, Takashi Tsukuba, JP 10 153
Yokota, Jiro Tsukuba, JP 8 415

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